|
|
anthocyanidin-3,5-O-diglucoside + 4-coumaroyl-CoA <=> an_anthocyanidin_3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside] + CoA
|
2.3.1.153
anthocyanin 5-(6'''-hydroxycinnamoyltransferase)
|
–
|
|
|
BRENDA:
BR1629
KEGG:
R05163
MetaCyc:
RXN-7945
|
|
|
|
4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.140
rosmarinate synthase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
BMK
|
|
BRENDA:
BR43994
KEGG:
R02416
MetaCyc:
2.3.1.133-RXN
|
|
|
|
4-coumaroyl-CoA + agmatine <=> H+ + CoA + 4-coumaroylagmatine
|
2.3.1.64
agmatine N4-coumaroyltransferase
|
–
|
MK
|
|
BRENDA:
BR44065
KEGG:
R01617
MetaCyc:
AGMATINE-N4-COUMAROYLTRANSFERASE-RXN
SABIO-RK:
1762
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> naringenin_chalcone + CO2 + CoA
|
2.3.1.159
acridone synthase
2.3.1.74
chalcone synthase
|
–
–
|
MK
|
|
BRENDA:
BR44076
KEGG:
R01613
MetaCyc:
NARINGENIN-CHALCONE-SYNTHASE-RXN
SABIO-RK:
1758
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> resveratrol + CoA + CO2
|
2.3.1.146
pinosylvin synthase
2.3.1.95
trihydroxystilbene synthase
|
–
–
|
MK
|
|
BRENDA:
BR44098
KEGG:
R01614
MetaCyc:
RXN-87
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA + NADPH <=> isoliquiritigenin + CoA + CO2 + NADP+ + H2O
|
2.3.1.170
6'-deoxychalcone synthase
|
–
|
MK
|
|
BRENDA:
BR48507
KEGG:
R06568
MetaCyc:
RXN-3142
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + H2O + H+ <=> CoA + bisdemethoxycurcumin + CO2
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
K
|
|
BRENDA:
BR50403
KEGG:
R10233
MetaCyc:
RXN-13958
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA + H2O <=> 4-hydroxybenzalacetone + CO2 + CoA
|
2.3.1.212
benzalacetone synthase
|
–
|
BM
|
|
BRENDA:
BR50404
KEGG:
R10234
MetaCyc:
RXN-8458
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> (4-coumaroyl)acetyl-CoA + CoA + CO2
|
2.3.1.218
phenylpropanoylacetyl-CoA synthase
|
–
|
MK
|
|
BRENDA:
BR50411
KEGG:
R08805
MetaCyc:
RXN-11220
|
|
|
|
4-coumaroyl-CoA + feruloylacetyl-CoA + H2O <=> demethoxycurcumin + CoA + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
K
|
|
BRENDA:
BR50412
KEGG:
R08809
MetaCyc:
RXN-11225
|
|
|
|
4-coumaroyl-CoA + (4-coumaroyl)acetyl-CoA + H2O <=> bisdemethoxycurcumin + CoA + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
K
|
|
BRENDA:
BR50413
KEGG:
R08807
MetaCyc:
RXN-11223
|
|
|
|
S-adenosyl-L-methionine + 4-coumaroyl-CoA <=> CoA + S-methyl-5''-thioadenosine + N-(4-coumaroyl)-L-homoserine_lactone + H+
|
2.3.1.229
4-coumaroyl-homoserine lactone synthase
|
–
|
|
|
BRENDA:
BR50759
KEGG:
R10529
MetaCyc:
RXN-14719
|
|
|
|
4-coumaroyl-CoA + spermidine <=> CoA + N1,N8-bis(4-coumaroyl)-spermidine + H+
|
2.3.1.249
spermidine dicoumaroyl transferase
|
–
|
|
|
BRENDA:
BR51401
KEGG:
R11200
MetaCyc:
RXN-16473
|
|
|
|
dihydro-4-coumaroyl-CoA + NADP+ <=> 4-coumaroyl-CoA + NADPH + H+
|
1.3.1.117
hydroxycinnamoyl-CoA reductase
|
–
|
MK
|
|
BRENDA:
BR52388
KEGG:
R12112
MetaCyc:
RXN-11467
|
|
|
|
4-coumaroyl-CoA + (R)-3-(4-hydroxyphenyl)lactate <=> p-coumaric_acid + (R)-3-(4-hydroxyphenyl)lactoyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
BM
|
|
BRENDA:
BR52901
KEGG:
R12492
MetaCyc:
RXN-19897
|
|
|
|
4-coumaroyl-CoA + 2-oxoglutarate + O2 <=> 2,4-dihydroxycinnamoyl-CoA + succinate + CO2
|
1.14.11.62
trans-4-coumaroyl-CoA 2-hydroxylase
|
–
|
MK
|
|
BRENDA:
BR52905
KEGG:
R12306
MetaCyc:
RXN-12963
|
|
|
|
(R)-3-(4-hydroxyphenyl)lactoyl-CoA <=> 4-coumaroyl-CoA + H2O
|
4.2.1.175
(R)-3-(aryl)lactoyl-CoA dehydratase
|
–
|
BM
|
|
BRENDA:
BR52948
KEGG:
R12488
MetaCyc:
RXN-19898
|
|
|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
BMK
|
|
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
4-coumaroyl-CoA + H2O <=> 4-hydroxybenzaldehyde + acetyl-CoA
|
4.1.2.61
feruloyl-CoA hydratase/lyase
|
–
|
|
|
BRENDA:
BS141629
MetaCyc:
RXN-21006
|
|
|
|
4-coumaroyl-CoA + NADPH + H+ <=> 4-coumaraldehyde + CoA + NADP+
|
1.2.1.44
cinnamoyl-CoA reductase
|
–
|
BMK
|
|
BRENDA:
BS189225;
BS388396
KEGG:
R01615
MetaCyc:
RXN-1101
SABIO-RK:
1760
|
|
|
|
4-coumaroyl-CoA + tyramine <=> H+ + hydroxycinnamoyltyramine + CoA
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
M
|
|
BRENDA:
BS320302
MetaCyc:
RXN-8715
SABIO-RK:
14777
|
|
|
|
4-coumaroyl-CoA + quinate <=> 5-O-p-coumaroylquinic_acid + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
|
BMK
|
|
BRENDA:
BS320439
KEGG:
R07432
MetaCyc:
RXN-2601
|
|
|
|
(R)-3-(4-hydroxyphenyl)lactate + 4-coumaroyl-CoA <=> 4-coumaroyl-4''-hydroxyphenyllactate + CoA
|
2.3.1
2.3.1.140
rosmarinate synthase
|
–
–
|
M
|
|
BRENDA:
BS320508
MetaCyc:
RXN-7626
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + H+ <=> 4-hydroxy-6-[(E)-2-(4-hydroxyphenyl)ethenyl]-2H-pyran-2-one + CO2 + CoA
|
2.3.1.151
2,3',4,6-tetrahydroxybenzophenone synthase
2.3.1.212
benzalacetone synthase
2.3.1.M47
|
–
–
–
|
M
|
|
BRENDA:
BS419941
MetaCyc:
RXN-7575
|
|
|
|
4-coumaroyl-CoA + 3-oxooctanoyl-CoA + H2O <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)deca-1,4-dien-3-one + CoA + CO2
|
2.3.1
2.3.1.211
bisdemethoxycurcumin synthase
|
–
–
|
M
|
|
BRENDA:
BS422576
MetaCyc:
RXN-12668
|
|
|
|
4-coumaroyl-CoA + cyanidin_3,5-di-O-beta-D-glucoside <=> shisonin + CoA
|
2.3.1
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
–
|
MK
|
|
BRENDA:
BS422598
KEGG:
R06545
MetaCyc:
RXN-8170
|
|
|
|
cyanidin_3-O-beta-D-glucoside + 4-coumaroyl-CoA <=> CoA + cyanidin_3-O-(6-O-(4-coumaroyl))-beta-D-glucoside
|
2.3.1
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
–
|
MK
|
|
BRENDA:
BS422599
KEGG:
R06544
MetaCyc:
RXN-15327;
RXN-8204
|
|
|
|
4-coumaroyl-CoA + an_anthocyanidin_3-O-beta-D-glucoside <=> CoA + an_anthocyanidin_3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside]
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BR50407
KEGG:
R10237
|
|
|
|
4-coumaroyl-CoA + putrescine <=> CoA + N-coumaroylputrescine
|
2.3.1
2.3.1.138
putrescine N-hydroxycinnamoyltransferase
2.3.1.64
agmatine N4-coumaroyltransferase
|
–
–
–
|
K
|
|
BRENDA:
BS320494
KEGG:
R09256
|
|
|
|
4-coumaroyl-CoA + delphinidin_3-O-beta-D-glucoside <=> CoA + delphinidin_3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside]
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
K
|
|
BRENDA:
BS422601
KEGG:
R07929
|
|
|
|
delphinidin_3,5-di-O-beta-D-glucoside + 4-coumaroyl-CoA <=> CoA + delphinidin_3-O-beta-D-glucoside-5-O-(6-O-4-coumaroyl)-beta-D-glucoside
|
2.3.1.153
anthocyanin 5-(6'''-hydroxycinnamoyltransferase)
|
–
|
K
|
|
BRENDA:
BS7665
KEGG:
R07883
|
|
|
|
cyanidin_3,5-di-O-beta-D-glucoside + 4-coumaroyl-CoA <=> CoA + cyanidin_3-O-beta-D-glucoside-5-O-(6-O-4-coumaroyl)-beta-D-glucoside
|
2.3.1.153
anthocyanin 5-(6'''-hydroxycinnamoyltransferase)
|
–
|
K
|
|
BRENDA:
BS7666
KEGG:
R07882
|
|
|
|
4-coumaroyl-CoA + spermidine <=> N1,N5,N10-Tricoumaroyl_spermidine + CoA + H+
|
2.3.1.M34
|
–
|
MK
|
|
KEGG:
R08983
MetaCyc:
RXN-11257
|
|
|
|
pelargonidin_3-O,5-O-di-beta-D-glucoside + 4-coumaroyl-CoA <=> Pelargonidin_3-O-beta-D-glucoside_5-O-(6-coumaroyl-beta-D-glucoside) + CoA
|
2.3.1.153
anthocyanin 5-(6'''-hydroxycinnamoyltransferase)
|
–
|
K
|
|
KEGG:
R07880
MetaCyc:
RXN-7843
|
|
|
|
4-coumaroyl-CoA + pelargonidin_3-O-beta-D-glucoside <=> Pelargonidin_3-(6-p-coumaroyl)glucoside + CoA
|
2.3.1
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
–
|
MK
|
|
KEGG:
R07927
MetaCyc:
RXN-7998
|
|
|
|
4-coumaroyl-CoA + CoA + H2O + NAD+ <=> H+ + 4-hydroxybenzoyl-CoA + acetyl-CoA + NADH
|
not assigned
|
–
|
K
|
|
KEGG:
R08767
MetaCyc:
RXN3O-1120
|
|
|
|
4-coumaroyl-CoA + serotonin <=> H+ + N-(4-coumaroyl)tryptamine + CoA
|
2.3.1.M35
|
–
|
M
|
|
MetaCyc:
RXN-8711
SABIO-RK:
14776
|
|
|
|
kaempferol_3-O-beta-D-glucosyl-(1-2)-beta-D-glucosyl-(1-2)-beta-D-glucoside + 4-coumaroyl-CoA <=> Kaempferol_3-O-[6-(4-coumaroyl)-beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside] + CoA
|
2.3.1.173
flavonol-3-O-triglucoside O-coumaroyltransferase
|
–
|
K
|
|
KEGG:
R06806
|
|
|
|
4-coumaroyl-CoA <=> caffeoyl-CoA
|
1.14.13
|
–
|
K
|
|
KEGG:
R07436
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + hexanoyl-CoA + H2O <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)deca-1,4-dien-3-one + 3 CoA + 2 CO2
|
not assigned
|
–
|
K
|
|
KEGG:
R08796
|
|
|
|
cinnamoyl-CoA + reduced_flavodoxin + O2 <=> 4-coumaroyl-CoA + flavin + H2O
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
K
|
|
KEGG:
R08815
|
|
|
|
4-coumaroyl-CoA + a_flavonol_3-O-beta-D-glucosyl-(1-2)-beta-D-glucosyl-(1-2)-beta-D-glucoside <=> CoA + flavonol_3-O-(6-(4-coumaroyl)-beta-D_glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside)
|
2.3.1.173
flavonol-3-O-triglucoside O-coumaroyltransferase
|
–
|
|
|
MetaCyc:
2.3.1.173-RXN
|
|
|
|
4-coumaroyl-CoA + H2O <=> 3S-(4-hydroxyphenyl)-3-hydroxy-propanoyl-CoA
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-11244
|
|
|
|
kaempferol_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> kaempferol_3-O-(4-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13948
|
|
|
|
kaempferol_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> kaempferol_3-O-(3-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13949
|
|
|
|
kaempferol_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> tiliroside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13950
|
|
|
|
tiliroside + 4-coumaroyl-CoA <=> kaempferol_3-O-(3,6-O-di-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13952
|
|
|
|
kaempferol_3-O-(6-O-feruloyl)-glucoside + 4-coumaroyl-CoA <=> kaempferol_3-O-(3-O-p-coumaroyl,_6-O-feruloyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13953
|
|
|
|
tiliroside + 4-coumaroyl-CoA <=> kaempferol_3-O-(4,6-O-di-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13954
|
|
|
|
4-coumaroyl-CoA + an_anthocyanidin_3-O-beta-D-glucoside <=> CoA + anthocyanidin-3-O-[6-O-(hydroxycinnamoyl)-beta-D-glucoside]
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
MetaCyc:
RXN-13959
|
|
|
|
isorhamnetin_3-O-glucoside + 4-coumaroyl-CoA <=> isorhamnetin_3-O-(4-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13977
|
|
|
|
isorhamnetin_3-O-glucoside + 4-coumaroyl-CoA <=> isorhamnetin_3-O-(3-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13978
|
|
|
|
isorhamnetin_3-O-glucoside + 4-coumaroyl-CoA <=> isorhamnetin_3-O-(6-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13979
|
|
|
|
isorhamnetin_3-O-(6-O-p-coumaroyl)-glucoside + 4-coumaroyl-CoA <=> isorhamnetin_3-O-(3,6-O-di-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13981
|
|
|
|
isorhamnetin_3-O-(6-O-feruloyl)-glucoside + 4-coumaroyl-CoA <=> isorhamnetin_3-O-(3-O-p-coumaroyl,_6-O-feruloyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13982
|
|
|
|
quercetin_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> quercetin_3-O-(4-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13983
|
|
|
|
quercetin_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> quercetin_3-O-(3''-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13984
|
|
|
|
quercetin_3-O-glucoside + 4-coumaroyl-CoA + H+ <=> quercetin_3-O-(6-O-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13985
|
|
|
|
quercetin_3-O-(6-O-p-coumaroyl)-glucoside + 4-coumaroyl-CoA <=> quercetin_3-O-(3,6-O-di-p-coumaroyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13987
|
|
|
|
quercetin_3-O-(6-O-feruloyl)-glucoside + 4-coumaroyl-CoA <=> quercetin_3-O-(3-O-p-coumaroyl,_6-O-feruloyl)-glucoside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-13988
|
|
|
|
cyanidin-3-O-sambubioside + 4-coumaroyl-CoA + H+ <=> cyanidin_3-O-(6-O-(4-coumaroyl))-beta-D-sambubioside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-15329
|
|
|
|
p-coumaryl_alcohol + 4-coumaroyl-CoA <=> 4-coumaryl-4-coumarate + CoA
|
2.3
|
–
|
M
|
|
MetaCyc:
RXN-16366
|
|
|
|
pelargonidin_3-O-beta-D-sambubioside + 4-coumaroyl-CoA <=> pelargonidin_3-O-(4-coumaroyl)-beta-D-sambubioside + CoA
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-16781
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA + H+ + polyketide-[acp] <=> (6E)-7-(4-hydroxyphenyl)-3,5-dioxohept-6-enoyl-[styrylpyrone_synthase] + CoA + CO2
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-21007
|
|
|
|
feruloyl_diketide + 4-coumaroyl-CoA + H+ <=> demethoxycurcumin + CoA + CO2
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-21156
|
|
|
|
4-coumaroyl-diketide + 4-coumaroyl-CoA + H+ <=> bisdemethoxycurcumin + CoA + CO2
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-21157
|
|
|
|
4-coumaroyl-CoA + 5-hydroxyanthranilate <=> avenanthramide_A + CoA
|
2.3.1.dt
|
–
|
M
|
|
MetaCyc:
RXN-21512
|
|
|
|
H+ + 4-coumaroyl-CoA + H2O + malonyl-CoA <=> CoA + CO2 + p-coumaroyltriacetate
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-7577
|
|
|
|
H+ + 4-coumaroyl-CoA + malonyl-CoA <=> 4-coumaroyltriacetic_acid_lactone + CoA + CO2
|
2.3.1
|
–
|
M
|
|
MetaCyc:
RXN-7822
|
|
|
|
4-coumaroyl-CoA + kaempferol_3-O-beta-D-glucosyl-(1->2)-glucosyl-(1->2)-beta-D-glucoside <=> kaempferol_3-O-[6-(4-coumaroyl)-beta-D-glucosyl-(1->2)-glucosyl-(1->2)-beta-D-glucoside + CoA
|
2.3.1.173
flavonol-3-O-triglucoside O-coumaroyltransferase
|
–
|
M
|
|
MetaCyc:
RXN-8291
|
|
|
|
4-coumaroyl-CoA + glycerol <=> CoA + 2-O-(4-coumaroyl)glycerol + 1-O-(4-coumaroyl)glycerol
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS420044
|
|
|
|
4-coumaroyl-CoA + catechol <=> CoA + 1-(4-coumaroyl)catechol
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435126
|
|
|
|
4-coumaroyl-CoA + (S)-malate <=> CoA + 2-O-(4-coumaryl)-L-malate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS408079
|
|
|
|
4-coumaroyl-CoA + isocitrate <=> CoA + 4-coumaroylisocitrate
|
2.3.1.126
isocitrate O-dihydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS451928
|
|
|
|
4-coumaroyl-CoA + tryptamine <=> CoA + N-(4-coumaroyl)tryptamine
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
|
|
BRENDA:
BS420046
|
|
|
|
4-coumaroyl-CoA + hydroquinone <=> CoA + 1-(4-coumaroyl)hydroquinone
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435129
|
|
|
|
4-coumaroyl-CoA + 2,3-Dihydroxybenzoate <=> CoA + 3-O-(4-coumaroyl)oxy-2-hydroxybenzoate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435121
|
|
|
|
4-coumaroyl-CoA + 3-Hydroxyanthranilate <=> CoA + 3-(4-coumaroyl)oxyanthranilate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS420038
|
|
|
|
4-coumaroyl-CoA + 3-Hydroxyanthranilate <=> CoA + N-(4-coumaroyl)-3-hydroxyanthranilate
|
2.3.1.144
anthranilate N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS420039
|
|
|
|
4-coumaroyl-CoA + 3-oxododecanoyl-CoA <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)tetradeca-1,4-dien-3-one + CoA + CO2 + H2O
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422578
|
|
|
|
malvidin_3-O-beta-D-glucoside + 4-coumaroyl-CoA <=> CoA + malvidin_3-O-(6-O-coumaroyl)-beta-D-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS435614
|
|
|
|
anthocyanidin-3-O-rutinoside_5-O-beta-D-glucoside + 4-coumaroyl-CoA <=> CoA + anthocyanidin_3-(p-coumaroyl)rhamnosylglucoside-5-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS387871
|
|
|
|
4-coumaroyl-CoA + D-tyrosine <=> CoA + N-(4-coumaroyl)-D-tyrosine
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS420043
|
|
|
|
4-coumaroyl-CoA + 4-(2-hydroxyethyl)phenol <=> CoA + 2-O-(4-coumaroyl)tyrosol
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS455046
|
|
|
|
4-coumaroyl-CoA + octopamine <=> CoA + N-(4-coumaroyl)octopamine
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
|
|
BRENDA:
BS320296
|
|
|
|
4-coumaroyl-CoA + 2,5-Dihydroxybenzoate <=> CoA + 5-O-(4-coumaroyl)gentisate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435128
|
|
|
|
4-coumaroyl-CoA + D-glucarate <=> CoA + p-coumaroylglucarate
|
2.3.1.131
glucarate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS320434
|
|
|
|
4-coumaroyl-CoA + Mandelate <=> CoA + 2-O-(4-coumaroyl)-3-phenyllactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS455043
|
|
|
|
4-coumaroyl-CoA + galactarate <=> CoA + O-p-coumaroylgalactarate
|
2.3.1.130
galactarate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS320431
|
|
|
|
4-coumaroyl-CoA + pelargonidin_3-O-beta-D-glucoside <=> CoA + pelargonidin_3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucoside]
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS422603
|
|
|
|
4-coumaroyl-CoA + pelargonidin_3-O,5-O-di-beta-D-glucoside <=> CoA + pelargonidin_3-O-[6-O-(4-hydroxycinnamoyl)-beta-D-glucosyl]-5-O-beta-D-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS422602
|
|
|
|
4-coumaroyl-CoA + Phenyllactate <=> CoA + 2-O-(4-coumaroyl)-3-phenyllactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS455044
|
|
|
|
4-coumaroyl-CoA + Tartronate <=> CoA + p-coumaroyltartronic_acid
|
2.3.1.106
tartronate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS320270
|
|
|
|
4-coumaroyl-CoA + 3-(3,4-Dihydroxyphenyl)lactate <=> CoA + 2-O-(4-coumaroyl)-3-(3,4-dihydroxyphenyl)lactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS320507
|
|
|
|
4-coumaroyl-CoA + 3-oxodecanoyl-CoA <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)dodeca-1,4-dien-3-one + CoA + CO2 + H2O
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422575
|
|
|
|
4-coumaroyl-CoA + D-phenyllactate <=> CoA + (R)-2-O-(4-coumaroyl)-3-phenyllactate
|
2.3.1.140
rosmarinate synthase
|
–
|
|
|
BRENDA:
BS420042
|
|
|
|
4-coumaroyl-CoA + D-glucono-1,5-lactone <=> CoA + O-p-coumaroylglucarolactone
|
2.3.1.132
glucarolactone O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS356073
|
|
|
|
4-coumaroyl-CoA + anthranilate <=> CoA + N-4-(coumaroyl)anthranilate
|
2.3.1.144
anthranilate N-benzoyltransferase
|
–
|
|
|
BRENDA:
BS320521
|
|
|
|
4-coumaroyl-CoA + 3-aminobenzoic_acid <=> CoA + 3-N-(4-coumaroyl)aminobenzoate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435123
|
|
|
|
4-coumaroyl-CoA + cinnamoyl-diketide-N-acetylcysteamine + H2O <=> CoA + cinnamoyl-4-coumaroyl-methane + N-acetylcysteamine
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422580
|
|
|
|
4-coumaroyl-CoA + a_flavonol_3-O-[beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside] <=> CoA + a_flavonol_3-O-[6-(4-coumaroyl)-beta-D-glucosyl-(1->2)-beta-D-glucosyl-(1->2)-beta-D-glucoside]
|
2.3.1.173
flavonol-3-O-triglucoside O-coumaroyltransferase
|
–
|
|
|
BRENDA:
BR48510
|
|
|
|
4-coumaroyl-CoA + 3,4-dihydroxybenzoate <=> CoA + 3-O-(4-coumaroyl)oxy-4-hydroxybenzoate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435122
|
|
|
|
4-coumaroyl-CoA + methylmalonyl-CoA + H2O <=> 2 CoA + 1-(4-hydroxyphenyl)pent-1-en-3-one + 2 CO2
|
2.3.1.212
benzalacetone synthase
|
–
|
|
|
BRENDA:
BS422574
|
|
|
|
4-coumaroyl-CoA + methylmalonyl-CoA <=> 1-(4-hydroxyphenyl)pent-1-en-3-one
|
2.3.1.74
chalcone synthase
|
–
|
|
|
BRENDA:
BS455040
|
|
|
|
4-coumaroyl-CoA + 2-Phenylethylamine <=> CoA + (2E)-3-(4-hydroxyphenyl)-N-(2-phenylethyl)prop-2-enamide
|
2.3.1.110
tyramine N-feruloyltransferase
|
–
|
|
|
BRENDA:
BS420045
|
|
|
|
4-coumaroyl-CoA + 3-oxotetradecanoyl-CoA <=> (1E,4Z)-5-hydroxy-1-(4-hydroxyphenyl)hexadeca-1,4-dien-3-one + CoA + CO2 + H2O
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422577
|
|
|
|
4-coumaroyl-CoA + 5-hydroxyanthranilate <=> CoA + 5-(4-coumaroyl)oxyanthranilate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS435125
|
|
|
|
4-coumaroyl-CoA + 3-hydroxybenzoate <=> CoA + 3-(4-coumaroyl)oxybenzoate
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
|
–
|
|
|
BRENDA:
BS420040
|
|
|
|
4-coumaroyl-CoA + 16-hydroxypalmitic_acid <=> CoA + (E)-16-(3-(4-hydroxyphenyl)acryloyloxy)hexadecanoic_acid
|
2.3.1.188
omega-hydroxypalmitate O-feruloyl transferase
|
–
|
|
|
BRENDA:
BS406275
|
|
|
|
4-coumaroyl-CoA + (4-coumaroyl)acetyl-CoA + H2O <=> 2 CoA + bidemethoxycurcumin + CO2
|
2.3.1.219
demethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS455041
|
|
|
|
4-coumaroyl-CoA + delphinidin_3,5-di-O-beta-D-glucoside <=> CoA + delphinidin_3-O-(4-coumaroyl)-beta-D-glucoside-5-O-beta-D-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS422600
|
|
|
|
delphinidin_3-rhamnosylglucoside-5-glucoside + 4-coumaroyl-CoA <=> CoA + delphinidin_3-O-[2-O-(4-coumaroyl)-alpha-L-rhamnosyl-(1->6)-beta-D-glucoside]
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS388513
|
|
|
|
petunidin_3-rhamnosylglucoside-5-glucoside + 4-coumaroyl-CoA <=> CoA + petunidin_3-(p-coumaroyl)rhamnosylglucoside-5-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS389531
|
|
|
|
malvidin_3-rhamnosylglucoside-5-glucoside + 4-coumaroyl-CoA <=> CoA + malvidin_3-(p-coumaroyl)rhamnosylglucoside-5-glucoside
|
2.3.1.215
anthocyanidin 3-O-glucoside 6''-O-acyltransferase
|
–
|
|
|
BRENDA:
BS389140
|
|
|
|
4-coumaroyl-CoA + H2O <=> p-coumaric_acid + CoA
|
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
|
|
|
BRENDA:
BS412641
|
|
|
|
4-coumaroyl-CoA <=> Vanillin + acetyl-CoA
|
4.1.2.61
feruloyl-CoA hydratase/lyase
|
–
|
|
|
BRENDA:
BS393062
|
|
|
|
malonyl-CoA + 4-coumaroyl-CoA + NADH <=> 6''-deoxychalcone + CoA + CO2 + NAD+
|
2.3.1.74
chalcone synthase
|
–
|
|
|
BRENDA:
BS321283
|
|
|
|
malonyl-CoA + 4-coumaroyl-CoA + NADPH <=> 5''-deoxyflavanone + CoA + CO2 + NADP+
|
2.3.1.74
chalcone synthase
|
–
|
|
|
BRENDA:
BS321284
|
|
|
|
4-coumaroyl-CoA + NADPH + CO2 + H+ <=> (2S)2-carboxy-3-(4-hydroxyphenyl)propionyl-CoA + NADP+
|
1.3.1.85
crotonyl-CoA carboxylase/reductase
|
–
|
|
|
BRENDA:
BS438837
|
|
|
|
4-coumaroyl-CoA + cinnamoyl-CoA + malonyl-CoA + H2O <=> 3 CoA + cinnamoyl-4-coumaroyl-methane + 2 CO2
|
2.3.1.211
bisdemethoxycurcumin synthase
|
–
|
|
|
BRENDA:
BS422579
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA <=> cis-2-acetylresveratrol + CoA + CO2
|
2.3.1.146
pinosylvin synthase
|
–
|
|
|
BRENDA:
BS408097
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA <=> 2-malonylresveratrol + CoA + CO2
|
2.3.1.146
pinosylvin synthase
|
–
|
|
|
BRENDA:
BS410027
|
|
|
|
malonyl-CoA + 4-coumaroyl-CoA <=> CoA + naringenin_chalcone
|
2.3.1.159
acridone synthase
2.3.1.74
chalcone synthase
|
–
–
|
|
|
BRENDA:
BS320547
|
|
|
|
3 malonyl-CoA + 4-coumaroyl-CoA <=> 4 CoA + resveratrol
|
2.3.1.95
trihydroxystilbene synthase
|
–
|
|
|
BRENDA:
BS435070
|
|
|
|
4-coumaroyl-CoA + malonyl-CoA <=> 4-coumaroyltriacetic_acid_lactone
|
2.3.1.74
chalcone synthase
|
–
|
|
|
BRENDA:
BS420047
|
|
|
|
3,4-dihydroxyphenylpropanoyl-CoA + p-coumaric_acid <=> 3,4-Dihydroxyphenylpropionate + 4-coumaroyl-CoA
|
2.8.3.23
caffeate CoA-transferase
|
–
|
|
|
BRENDA:
BS431336
|
|